Volume of a divisor on a smooth projective surface Let $X$ be a  smooth projective surface (over complex numbers). Let $D$ be a divisor on $X$. Then we know that its volume is defined as $$\text{vol}_X(D):= \lim \sup_{m \rightarrow \infty} \frac{h^0(X, \mathcal O_X(mD))}{{m^2}/2}.$$
Suppose that, for a divisor $D$ on $X$, it is known that $\text{vol}_X(D)=D^2$, where $D^2$ stands for its self-intersection number.

Question. What does this signify algebro-geometrically? And what are some interesting properties of $D$ that one can deduce
once the volume is explicitly known?

 A: At least for effective divisors, the answer is strongly related to Zariski decomposition.
If $D$ is an effective divisor on a smooth surface $X$, Zariski proved in [Z62] that there exists a unique decomposition $D=P + N$, where

*

*$P$ is a nef $\mathbb{Q}$-divisor

*$N$ is an effective $\mathbb{Q}$-divisor

*$PC=0$ for every curve $C$ appearing in $\operatorname{Supp}(N)$

*if $N \neq 0$ and $\operatorname{Supp}(N)=C_1 \cup \ldots \cup C_k$, then the intersection form $I(C_1, \ldots, C_k)$ is negative defined.

Furthermore, one also shows that, for all positive integers $m$, the natural map $$H^0(X,  \left \lfloor{mP}\right \rfloor) \to H^0(X, \, mD) $$ is an isomorphism. This means that "$P$ carries all sections of $D$" and so $$\operatorname{vol}_X(D)=\operatorname{vol}_X(P)= P^2,$$ where the last equality is a consequence of the asymptotic form of Riemann-Roch theorem, because $P$ is nef.
Thus, $\operatorname{vol}_X(D)=D^2$ is equivalent to $D^2=P^2$; since $PN=0$, this happens if and only if $N^2=0$. But the intersection form must be negative defined on $N$ when $N \neq 0$, hence the only possibility is $N=0$, namely, $D=P$.
Summing up:

given an effective divisor $D$ on a smooth surface $X$, we have
$\operatorname{vol}_X(D)=D^2$ if and only if $D$ is nef.

More generally, the difference $$D^2-\operatorname{vol}_X(D)$$ equals the self-intersection $N^2$ of the negative part of the Zariski decomposition of $D$, so it can be seen as a measure of how much "$D$ fails to be nef".
References.
[Z62] O. Zariski The theorem of Riemann-Roch for high multiples of an effective divisor on an algebraic surface, Ann. Math. (2) 76, 560-615 (1962). ZBL0124.37001.
