Definitions/Background
Suppose $S$ is a scheme and $D\subseteq S$ is an irreducible effective Cartier divisor. Then $D$ induces a morphism from $S$ to the stack $[\mathbb A^1/\mathbb G_m]$ (a morphism to this stack is the data of a line bundle and a global section of the line bundle, modulo scaling). For a positive integer $k$, the root stack $\sqrt[k]{D/S}$ is defined as the fiber product
$\begin{matrix} \sqrt[k]{D/S} & \longrightarrow & [\mathbb A^1/\mathbb G_m] \\ p\downarrow & & \downarrow \wedge k \\ S & \longrightarrow & [\mathbb A^1/\mathbb G_m] \end{matrix}$
where the map $\wedge k: [\mathbb A^1/\mathbb G_m]\to [\mathbb A^1/\mathbb G_m]$ is induced by the maps $x\mapsto x^k$ (on $\mathbb A^1$) and $t\mapsto t^k$ (on $\mathbb G_m$). The morphism $p:\sqrt[k]{D/S}\to S$ is a coarse moduli space and is an isomorphism over $S\smallsetminus D$. Moreover, there is a divisor $D'$ on $\sqrt[k]{D/S}$ such that $p^*D$ is $kD'$.
The data of a morphism from $T$ to $\sqrt[k]{D/S}$ is equivalent to the data a morphism $f:T\to S$ and a divisor $E$ on $T$ such that $f^*D = kE$.
The question
Suppose $\mathcal X$ is a DM stack, that $f:\mathcal X\to S$ is a coarse moduli space, that $f$ is an isomorphism over $S\smallsetminus D$, and that $f^*D = kE$ for an irreducible Cartier divisor $E$ on $\mathcal X$. Is the induced morphism $\mathcal X\to \sqrt[k]{D/S}$ an isomorphism?
I get the strong impression that the answer should be "yes", at least if additional conditions are placed on $\mathcal X$.
A counterexample
Here's a counterexample to show that some additional condition needs to be put on $\mathcal X$. Take $G$ to be $\mathbb A^1$ with a doubled origin, viewed as a group scheme over $\mathbb A^1$. Then $\mathcal X=[\mathbb A^1/G]\to \mathbb A^1$ is a coarse moduli space ("there's a $B(\mathbb Z/2)$ at the origin"). If we take $D\subseteq \mathbb A^1$ to be the origin, then the pullback to $\mathcal X$ is the closed $B(\mathbb Z/2)$ with multiplicity 1. Yet the induced morphism from $\mathcal X$ to $\sqrt[1]{D/\mathbb A^1}\cong \mathbb A^1$ is not an isomorphism.
In this case, $\mathcal X$ is a smooth DM stack, but has non-separated diagonal.