I think your property is true and can be shown recursively depending on the size $n$ of the graph.
Existence
For $n=2$ well one of the sequences has to be (0,0), so the other one is equal to $c$: it works just fine.
Now suppose that works for any valid sequence of length $n-1$ for some integer $n>2$. Take valid degree sequences $a$, $b$, $c$ of size $n$. Build any simple graph $G=(V,E)$ following sequence $c$.
Remove whichever node $u$ and its adjacent edges $U$. It will change the degree distrubution of its neighbours $N_u$ in the remaining graph. Define sequences $c'$, $a'$ and $b'$, copies of $c$, $a$ and $b$ except:
$$\forall v\in N_u, c'_v=c_v-1$$
$$\forall v\in N_u\text{ st }a_v>0, a'_v=a_v-1 $$
$$\forall v\in N_u\text{ st }a_v=0, b'_v=b_v-1 $$
The edges in $U$ can be separated in $E_a$ and $E_b$ depending on whether they impact distribution $a'$ or $b'$:
$$E_a=\{(u,v)\in U \:|\: a_v>0\}$$
$$E_b=\{(u,v)\in U \:|\: a_v=0\}$$
By construction, we have $\forall v\in V, c'_v=a'_v+b'_v$, and $a',b',c'$ are valid sequences of size $n-1$. This is not necessarily true: the sequences may not be valid, so the recursion is wrong.
By assumption, we can build a graph $G'=(V',E')$ such that:
- $V'=V\backslash\{u\}$
- $E'=E'_a\cup E'_b$ and $E'_a\cap E'_b=\emptyset$
- $G'$ follows distribution $c'$, $G'_a=(V',E'_a)$ follows distribution $a'$ and $G'_b=(V',E'_b)$ follows distribution $b'$
Finally, you add the node $u$ and its former edges to obtain the graph $G^*=(V,E'\cup U)$. The partition of edges is $E_a^*=E_a\cup E'_a$ and $E_b^*=E_b\cup E'_b$, which satisfies all the properties.
So this decomposition exists for distributions of size $n$.
Construction
This recursion provides a constructive process. If distributions of size $n$ are given, assuming they are valid, you can select a random node to remove, apply the procedure on the remaining graph, and then add the extra edges.
Note that the above definition of $E_a$ and $E_b$ is not symmetrical: it would be more balanced to choose at random if an edge of $U$ is affected to $E_a$ or $E_b$.
If $u$ is also chosen at random, and the case $n=2$ forces uniformly $a=c$ or $b=c$, then it may be considered as "uniform". However in my opinion, this concept needs to be clearly defined. Moreover, the recursion may not yield all the possible constructions.
Cheers!