$\DeclareMathOperator{\Inn}{\operatorname{Inn}}\DeclareMathOperator{\Aut}{\operatorname{Aut}}\DeclareMathOperator{\Out}{\operatorname{Out}}\DeclareMathOperator{\g}{\mathfrak{g}}$According to Wikipedia, outer automorphisms as symmetries of a Dynkin diagram follows from the general fact, that for a complex or real simple Lie algebra $\g$, the automorphism group $\Aut(\g)$ is a semidirect product of $$\Inn(\g) \rtimes \Out(\g)$$
i.e., the short exact sequence splits:
$${{1 ⟶ \Inn(\g) ⟶ \Aut(\g) ⟶ \Out(\g) ⟶ 1}}$$
In the complex simple Lie algebras, this is a classical result (Fulton-Harris 1991).
In the real simple Lie algebra, this fact has been proven as recently as 2010 (?). Cited this Ref: http://www.heldermann.de/JLT/JLT20/JLT204/jlt20035.htm by H. Gündogan.
> Question: Why the complex simple Lie algebras, we already know $\Aut(\g)=\Inn(\g) \rtimes \Out(\g)$, but it took a late recent work in 2010 to settle that the real simple Lie algebra also has $\Aut(\g)=\Inn(\g) \rtimes \Out(\g)$? (Especially given the following facts that the complex and real simple Lie algebras seem not be so different?) Facts:
Complex Lie algebra is a Lie algebra over the field $F$ as a complex $\mathbb{C}$.
Real Lie algebra is a Lie algebra over the field $F$ as a real $\mathbb{R}$.
Given a complex Lie algebra $\mathfrak g$, a real Lie algebra $\mathfrak{g}_0$ is said to be a real form of $\mathfrak g$ if the complexification $$\mathfrak{g}_0 \otimes_{\mathbb{R}} \mathbb{C} \simeq \mathfrak{g}$$ is isomorphic to $\mathfrak{g}$.