Let $S^3 \rightarrow S^2$ be the Hopf fibration. Can we recover $\pi_2(S^2)$ of $S^2$ from the simplicial set $X : \Delta^{op} \rightarrow \text{Set}$, $$ X(n) = \pi_0 (S^3 \times_{S^2} \cdots \times_{S^2} S^3) $$ $X$ is $\pi_0$ of the Čech nerve?
$S^3 \rightarrow S^2$ is not a good cover, but it does have $\pi_2, \pi_1, \pi_0 = 0$. So another way of thinking about this is whether $S^3 \rightarrow S^2$ acts enough like a good cover to recover $\pi_2(S^2)$.
In general, I am interested in categories like the category of schemes, which lacks good covers with which to tell the homotopy type $\pi_n(\text{Spec}(\mathbb{Z}))$. In absence of such good covers, one might hope to take some kind of limit over all of the covers, which better and better approximate a contractible one. This would be the next best thing to having a good cover, in the sense of Čech cohomology.