Let $G$ be a simple undirected graph, $f(v, u)$ be the number of simple paths between $u$ and $v$ in $G$, $f(G) = \max f(v, u)$ over all pairs of vertices $v, u \in G$.
A recent IOI problem utilized the fact that there is no graph with $f(G) = 3$. Are there any other values of $k \geq 1$ such that no graph with $f(G) = k$ exists?
Computationally, all positive $k \neq 3$ not exceeding $50$ have $f(G) = k$ with $G$ having at most $8$ vertices (in fact, only $k = 45$ requires more than $7$).