The standard simplices $\Delta^n \subset \{\mathbf{x}\in\mathbb{R}^{n+1}\mid x_0 + \ldots + x_n =1 \} =: \mathbb{A}^n$ carry two natural sorts of smooth differential forms:
Those differential forms on the interior of $\Delta^n$ that extend smoothly to a neighbourhood of $\Delta^n$ in $\mathbb{A}^n$ (this definition is used for instance by Dupont in his book Curvature and Characteristic Classes). This is implicitly using Whitney's extension theorem, I think.
Consider $\Delta^n$ as a diffeological subspace of $\mathbb{A}^n$, where a function $\phi\colon \mathbb{R}^k \to \Delta^n$ is a plot if and only if the composite $\mathbb{R}^k \to \Delta^n \hookrightarrow \mathbb{A}^n$ is smooth. A differential form $\omega$ on $\Delta^n$ then consists of the data of a differential form $\phi^*\omega$ for each plot $\phi$ with a compatibility condition when a plot factors through another via a smooth map between Euclidean spaces.
The first of these is more of a "maps out" viewpoint, and probably corresponds to a natural smooth space structure defined via smooth real-valued functions. The second is a "maps in" viewpoint. Note that the $D$-topology arising from the diffeology in 2. above is the standard topology on the simplex. We then get a cochain complex of differential forms of each type, as exterior differentiation can be defined in the more-or-less obvious way in each case.
My question is: how do these relate? Is one a subcomplex of the other? Or are they quasi-isomorphic, via a third cochain complex?
The motivation is that Dupont's simplicial differential forms on semisimplicial manifolds $X_\bullet$ look like they should be differential forms on the fat geometric realisation considered as a diffeological space, since a simplicial differential form is more or less descent data for the sheaf of differential forms and the 'cover' $\coprod_{n\geq 0} \Delta^n\times X_n \to ||X_\bullet||$, assuming the first definition above. However, if his differential forms on $\Delta^n$ (or more precisely on $\Delta^n\times X_n$) aren't diffeological differential forms, they don't give a form on $||X_\bullet||$ as a diffeological space. I guess all we really need is a map of cochain complexes from the first to the second given above.