I've read that the set of real numbers R is uncountable. It was proved by contradiction. A number x that is not in the f(n) side was constructed. Ultimately it was said that "x is not f(n) for any n because it differs from f(n) in the nth fractional digit. I can't understand the last part. I understand what is being said but don't see how it proves that R is uncountable.

$\begingroup$ Please see the faq for suggestions of sites where this question is more appropriate  mathoverflow.net/faq#whatnot $\endgroup$ – François G. Dorais♦ Aug 8 '10 at 14:22
Assume the interval $[0,1)$ is countable. Then we can write down all numbers like that:
 $a_0 = 0.a_{0,0}a_{0,1}a_{0,2}\dots$
 $a_1 = 0.a_{1,0}a_{1,1}a_{1,2}\dots$
 $a_2 = 0.a_{2,0}a_{2,1}a_{2,2}\dots$
 $\dots$
Now we construct a new number $b=0.b_0b_1b_2\dots$ in the following way. We look at $a_{ii}$. If this digit is $1$, then $b_i=2$, otherwise we set $b_i=1$. Therefore we constructed a now number, that is not in our list of $a_i$, since it differs from each number in one position. But the number $b$ is clearly in the interval $[0,1)$ and we assumed, that we have written down all numbers. Contradiction, i.e., the set was not countable.
And since $[0,1) \subseteq \mathbb{R}$, the real numbers are also not countable.
Edit. Using the notation of the original posting: $b=x$ and $f(n)=a_n$.
It is an indirect proof starting with the assumption that, contrary to the statement of the theorem, there does exist a surjection $f:\{0,1,\dots\}\to R$ of the natural numbers onto the reals. Given $f$, with clever manipulations, we exhibit a real number that is not equal to any value $f(n)$, and so $f$ is not onto the reals a contradiction. In indirect proofs, reaching a contradition is fine, as that shows the impossiblity of the negation of the statement.

3$\begingroup$ As in one of the other threads here, maybe it would be better to cast it in DIRECT form like this: If $f \colon \mathbb{N} \to \mathbb{R}$, then there is some real number not in the range of $f$ $\endgroup$ – Gerald Edgar Aug 8 '10 at 17:00