The simplest "non-trivial" example is $$z\mapsto \int_0^ze^{-\zeta^2}d\zeta:\quad C\to C.$$
It is surjective, and not ramified. But it is certainly not a covering because every covering over a simply connected surface is a homeomorphism.
You can make the target surface compact if you wish. Consider the map from $C$ to
$S$, where $S$ is the Riemann sphere, $f(z)=y_1/y_0$, where
$y_j$ are two linearly independent solutions of the Airy equation
$$y''=zy.$$ It is also surjective and unramified: $f'=-W(y_1,y_0)/y_0^2$,
where $W$ is the Wronskian determinant which is constant.
Unlike in the example of Dan Petersen, all my surfaces are simply connected.