As Igor mentions in the comments, this is really a question about deformations of the multiplication map of the exterior algebra in the space of associative multiplications. Since this is a pretty general story, let me try to sketch how it works in this case.
Let's fix some field $k$ and a $k$-algebra $(A,\mu)$. We want to understand deformations of $(A,\mu)$, and to start only infinitesimal deformations. For this we fix an Artinian augmented $k$-algebra $R\to k$ and build a groupoid $\operatorname{Def}_R$: objects are flat $R$-algebras $B$ with an isomorphism $\rho: B\otimes_R k\cong A$, and morphisms from $(B,\rho)$ to $(B',\rho')$ are isomorphisms of $R$-algebras over $k$.
$R$ being Artinian just means that $R \cong k\oplus\mathfrak m$, with $\mathfrak m$ being nilpotent and finite-dimensional. In fact, one does not lose all that much by restricting to $R_n = k[\hbar]/(\hbar^{n+1})$. By flatness, any $R_n$-deformation is of the form $B\cong R_n\otimes_k A\cong A[\hbar]/(\hbar^{n+1})$, but with an interesting multiplication $\mu_{B}$. It is determined by $\mu_B(a,a') = \sum_{i=0}^n\hbar^i\mu_i(a,a')$ for some maps $\mu_i:A\otimes_k A\to A$. Similarly, any automorphism $\lambda$ of $B$ is determined by $\lambda(a) = \sum_{i=0}^n\hbar^n\lambda_i(a)$ for some maps $\lambda_i:A\to A$. Then the condition that $\mu_B$ is associative leads to the following constraints:
- $\mu_0 = \mu$ by checking compatibility with $\rho$. From now on, I'll write $\cdot = \mu$. Similarly, $\lambda_0 = \operatorname{id}$.
- $\mu_1(f,g)h + \mu_1(fg,h) = f\mu_1(g,h) + \mu_1(f,gh)$, and $\lambda$ is a morphism from $\mu_1$ to $\mu_2$ iff $\mu_1(f,g) - \mu_2(f,g) = \lambda_1(fg) - f\lambda_1(g) - \lambda_1(f)g$. The first condition is that $\mu_1$ is a closed $1$-cocycle in the Hochschild chain complex $C^n(A) = \operatorname{Hom}(A^{\otimes(n+1)},A)$ with differential
$$
\mathrm d\mu(a_0,\dots,a_{n+1}) = a_0\mu(a_1,\dots,a_n) + \sum_{i=0}^{n-1} (-1)^{i+1}\mu(a_0,\dots,a_ia_{i+1},\dots,a_n) + (-1)^{n+1}\mu(a_0,\dots,a_{n-1})a_n\ .
$$
The multiplications of two such cocycles are isomorphic iff the cocycles are cohomologous. In this case the isomorphisms are a torsor over the set of closed $0$-cycles. All in all, the category $\operatorname{Def}_{k[x]/x^2}$ has objects in bijection with $HH^1(A)$, and each object has automorphism group $HH^0(A)$, where $HH^i(A) = H^i(C^*(A))$.
- $f\mu_2(g,h) - \mu_2(fg,h) + \mu_2(f,gh) - \mu_2(f,g)h = \mu_1(f,\mu_1(g,h)) - \mu_1(\mu_1(f,g),h)$. Thus given a first-order deformation $\mu_1$, one may form the element $\mu_1(-,\mu_1(-,-)) - \mu_1(\mu_1(-,-),-)$, which one can check to be a closed $2$-cocycle. The existence of $\mu_2$ is equivalent to the corresponding cohomology class vanishing. Thus for every first-order deformation there is an obstruction lying in $HH^2(A)$ which vanishes iff this first-order deformation extends to a second-order deformation. In this case the extensions are a torsor over $HH^1(A)$, and similarly for the automorphisms.
- This story continues: If we have found $\mu_1,\dots,\mu_n$, the existence of $\mu_{n+1}$ is equivalent to some obstruction class in $HH^2(A)$ vanishing, in which case the posible extensions are a torsor over $HH^1(A)$. Note however that the obstruction depends on all previous choices.
In fact, essentially all of these formal deformation problems arise in the following way (at least if $k$ is characteristic $0$): One has a dgla $(\mathfrak g,[-,-])$ and a natural isomorphism $\operatorname{Def}_{k\oplus\mathfrak m} \cong \{x\in \mathfrak m\otimes \mathfrak g^1\mid \mathrm dx + \frac{1}{2}[x,x] = 0\}//\mathfrak m\otimes \mathfrak g^0$, where the nilpotent Lie algebra $\mathfrak m\otimes \mathfrak g^0$ acts on this set of "Maurer-Cartan elements" by the Lie bracket and one takes the action groupoid of the action of the corresponding nilpotent Lie group. In our case the dgla is $C^*(A)$ equipped with the Gerstenhaber bracket which takes two cocycles and takes the sum over all ways to plug one into the other (with some signs).
In general, the deformation functor only depends on the dgla up to quasiisomorphism. This has one important consequence: If $\mathfrak g$ is formal, i.e. quasiisomorphic to its cohomology, then a Maurer-Cartan element of $\mathfrak g$ is "the same" as an element $x\in H^1(\mathfrak g)$ satisfying $[x,x] = 0$, i.e. a first-order deformation which extends to a second-order deformation. This then gives rise to a Maurer-Cartan element for any $R$, i.e. a lift to arbitrarily high order in $\hbar$, without having to check whether any more obstructions vanish! One can then put all of these lifts together to obtain an associative multiplication $\mu_\hbar = \mu + \cdots$ on $A[[\hbar]]$.
For a differential geometer, the most interesting case is that $A = C^\infty(M)$. In this case one should restrict to the subcomplex of the Hochschild complex of maps $C^\infty(M)^{\otimes(n+1)}\to C^\infty(M)$ which are differential operators in each variable. The Hochschild-Kostant-Rosenberg theorem computes the homology of this complex as polyvector fields $\oplus_{i\ge 1} \Gamma(M,\Lambda^i TM)$. The bracket on the homology groups is the Schouten bracket (extension of the Lie bracket as a biderivation). Amazingly, as proven by Kontsevich this dgla is actually formal! By the previous discussion this means that a first-order deformation, i.e. a biderivation $\pi\in\Gamma(M,\Lambda^2 TM)$, extends to all orders iff it extends to a second-order deformation, i.e. iff $[\pi,\pi] = 0$, iff $f\otimes g\mapsto \{f,g\} = \pi(\mathrm df,\mathrm dg)$ is a Poisson structure on $M$. This is called deformation quantization since quantization should associate to each function $f$ on $M$ an operator $\widehat f$ on some Hilbert space such that $[\widehat f,\widehat g] = \hbar \widehat{\{f,g\}} + O(\hbar^2)$. Deformation quantization does away with the Hilbert space and formally expands $\widehat f \cdot \widehat g = \widehat{f\cdot g} + \sum_{i\ge 1}\hbar^i\widehat{\mu_i(f,g)}$.
What does any of this have to do with your question about Clifford algebras? One can think of the graded commutative algebra $\Lambda^*V$ as functions on the supermanifold $\Pi V^\vee$ ("$V$ dual in odd degree"). The metric is a graded antisymmetric bilinear form on $V^\vee$ and hence induces a symplectic, and by extension Poisson, structure on this supermanifold, which by the previous discussion has an essentially unique deformation quantization. In fact, one can give an explicit formula for it by putting the right "fermion signs" into the Moyal product. This is a very special deformation quantization since only finitely many $\mu_i$ are nonzero. Thus for any value of $\hbar$ the series $\sum_{i\ge 0}\hbar^i \mu_i$ converges, and one may set $\hbar = 1$ to recover the Clifford algebra.