Examples of schemes $S$ with $H^{3}(S,\mathbb G_{m})=0$ The examples I have are: $S$ is equal to the spectrum of a global field; or a proper non-empty open subscheme of the spectrum of the ring of integers $\mathcal O_{K}$ of a number field $K$ (proper means $S$ is not all of ${\rm Spec}\,\mathcal O_{K}$); or $S$ is a non-empty open subscheme of a smooth, complete and irreducible curve over a finite field. Can anyone supply other examples, please?
 A: There's some information on the groups $H^q(S,\mathbb{G}_m)$ in Grothendieck's Le groupe de Brauer, II in Dix Exposés.  Proposition 1.4 says that if $S$ is regular then these groups are torsion for $q \ge 2$.  Corollaire 3.2 says that, under suitable finiteness hypotheses, the Kummer sequence gives isomorphisms $H^q(S,\mathbb{G}_m)[\ell^\infty] \cong H^q(S,\mu_{\ell^\infty})$ for $q \ge 3$ and $\ell$ invertible on $S$.  These finiteness hypotheses are satisfied, for example, if $S$ is either proper or smooth over a field that is either separably closed or finite.
Using this you can find plenty of examples with $H^3(S,\mathbb{G}_m)=0$, such as any projective space over an algebraically closed field of characteristic zero: the standard calculation of the cohomology of projective space gives $H^3(\mathbb{P}^m,\mu_n)=0$ for all $n$.
A: Let $\pi: S' \to S$ be a smooth projective relative curve with $S$ a regular variety. The $\mathrm{R}^q\pi_*\mathbf{G}_m = 0$ for $q > 1$, so there is an exact sequence coming from the Leray spectral sequence $$\mathrm{H}^2(S', \mathbf{G}_m) \to \mathrm{H}^1(S,\mathrm{R}^1\pi_*\mathbf{G}_m) \to \mathrm{H}^3(S,\mathbf{G}_m) \stackrel{\pi^*}{\to} \mathrm{H}^3(S', \mathbf{G}_m) \to \mathrm{H}^2(S,\mathrm{R}^1\pi_*\mathbf{G}_m) \to \mathrm{H}^4(S, \mathbf{G}_m).$$
