Criterion for alternation of the linking form I was recently informed by a source of the following fact: 
Theorem 1: The linking form on an orientable smooth 5-manifold $M$ is alternating if and only if $M$ is spin$^{\mathbb{C}}$.
Question 1: Does anybody know a reference/attribution for this fact? I've poked around online and in the library, and asked my usual go-to experts, but found nothing. (This page gives a reference to a criterion of Wall in the simply-connected case, but not the general one.)
I'm not in a position to be able to ask my source for a reference, but I'm pretty confident that Theorem 1 is correct because I think I have a proof. In fact the proof gives a criterion for the linking form on any orientable, odd-dimensional topological manifold to be alternating, which specializes to the above fact for smooth 5-manifolds. 
Question 2: Is such a criterion already known? Written down? Is it remotely interesting? 
 A: This is not an answer, but too long for a comment, and hopefully of some use. 
I believe the theorem you mention should be true for any 5-dimensional Poincaré duality space $X$. You can define the linking form on the torsion group $H^3(X,\mathbb{Z})_{\rm tor}$ (which is isomorphic to $H_2(X, \mathbb{Z})_{\rm tor}$ via the Poincaré duality structure) by setting $(x,y) = x' \cup y$, where $x' \in H^2(X,\mathbb{Q}/\mathbb{Z})$ maps to $x$ under the boundary map $\partial: H^2(X,\mathbb{Q}/\mathbb{Z}) \to H^3(X,\mathbb{Z})$ associated to the short exact sequence $0 \to \mathbb{Z} \to \mathbb{Q} \to \mathbb{Q}/\mathbb{Z} \to 0$. 
It should then be true that $(x,x) = (x,\partial \overline{w}_2) = x'\cup \partial \overline{w}_2$, where $\overline{w}_2$ is the image in $H^2(X,\mathbb{Q}/\mathbb{Z})$ of the second Stiefel-Whitney class $w_2 \in H^2(X,\mathbb{Z}/2)$ of the Spivak normal bundle. This would imply that the linking form is alternating if and only if $\partial \overline{w}_2$ vanishes in $H^3(X,\mathbb{Z})_{\rm tor} \subseteq H^3(X,\mathbb{Z})$, which, in turn, is equivalent to $w_2$ lifting to $H^2(X,\mathbb{Z})$. In the case of smooth manifolds this is the same as admitting a ${\rm spin}^{\mathbb{C}}$-structure.
For simply-connected 5-dimensional Poincaré duality spaces this is proved in Stöcker's paper from 1982 entitled "On the structure of 5-dimensional Poincaré duality spaces", but I was not able to find a proof for the general case.
It's possible that there is a small gap in the literature here, so it sounds to me that if you have a proof (in either the smooth, topological or Poincaré setting) it would be great if you write it up and publish it. I would certainly be interested to read it.
A: The final sentence of Theorem 1 of Browder's Remark on the Poincaré Duality Theorem states that a five-dimensional space $X$ with Poincaré duality has $H_2(X) = F + T + T + \mathbb{Z}_2$, where $F$ is free and $T$ is torsion, if and only if $w_3 \neq 0$. If $b$ denotes the linking form and $x$ is the generator of $\mathbb{Z}_2$, then $b(x, x) = \frac{1}{2}$ so $b$ is not alternating. Therefore, if $b$ is alternating, then $w_3 = 0$ which is equivalent to $w_2$ having an integral lift (which is equivalent to spin${}^c$ in the smooth case).
I don't know of a reference for the converse. However, if $H_2(X)$ has no two-torsion, then it is spin${}^c$ and the fact that the linking form is alternating follows from the classification of non-singular anti-symmetric linking forms; see here.
