The answer depends on what you mean by "quantities"! As José demonstrated, there are no polynomial absolute invariants, essentially because of homogeneity, however, there are plenty of rational ones, obtained as fractions $F/G,$ where $F$ and $G$ are polynomial relative invariants of the same weight $k:$
$$ F(g\cdot f)=(\det g)^k F(f),\ G(g\cdot f)=(\det g)^k G(f), \quad g\in GL(V).$$
Your dimension count is one of the common false believes. In fact, sanity is restored when working with rational functions, for
$$ \operatorname{tr\ deg} K(X)^G=\operatorname{tr\ deg} K(X)-\dim O_x,$$
where $X$ is an irreducible algebraic variety over an alg. closed field $K$ of char 0 with an action of an algebraic group $G$, $O_x=G\cdot x$ is a generic orbit, $G_x$ is the stabilizer of $x$, $\dim O_x=\dim G-\dim G_x.$ In fact, rational invariants always separate generic orbits.1 What goes wrong with polynomial invariants is that orbits need not be Zariski closed. In your example, due to the presence of dilations, Zariski closure of every orbit contains zero. A $G$-invariant polynomial function $F$ is constant on any orbit $O$ and hence its value at any point $x\in O$ is equal to $F(0),$ so $F$ is constant.
Another way to resolve the issue is to replace the group $G$ with its subgroup $[G,G]$, which is the inter-section of the kernels of all 1-dimensional representations of $G$, thus replace $Gl(V)$ with $SL(V)$ om the example. After the $GL(V)$-equivariant identification $Hom(V,V\otimes V)\simeq V^*\otimes V\otimes V$ and polarization, which replaces a homogeneous degree $d$ polynomial function on $W$ with a multilinear map with $d$ arguments $W^\otimes d\to K$, the question reduces to finding multilinear $SL(V)$-invariants. Classical invariant theory shows that they are all obtained by composing $GL(V)$-invariant contractions $V^* \otimes V\to K,$ $\xi\otimes v\mapsto \xi(v)$ and expansions $K\to V^*\otimes V,$ $1\mapsto \sum e_i^*\otimes e_i$, permutations, symmetrizations, antisymmetrizations, and the $SL(V)$-invariant determinants $V^{\otimes k} \to K,$ $v_1\otimes\ldots\otimes v_k\mapsto \det[v_1|\ldots|v_k],$ $k=\dim V.$ Explicit formulas are a bit messy.
Footnotes
1See Vinberg and Popov's article on invariant theory in Algebraic Geometry 4 volume of the yellow Russian Math Encyclopaedia.