The Picard group of a semisimple algebraic group in positive characteristic Let $k$ be a field of positive characteristic and let $G$ be a connected semisimple algebraic group over $k$ with fundamental group $\mu$. Note that $\mu$ can be non-smooth. It is stated in Sansuc's 1981 Crelle paper Groupe de Brauer et arithmétique des groupes algébriques..., Lemma 6.9(iii), p.41, that ${\rm Pic}\, G=\mu^{*}(k)$ is the group of $k$-characters of $\mu$. Sansuc refers the reader to the Fossum-Iversen paper On Picard groups of algebraic fiber spaces, Proposition 4.6, for this. Now, it is not clear to me that the latter paper really works at the required level of generality. To confuse matters even more (for me), Raynaud, in his thesis (Lecture Notes in Math. 119), discusses in particular the canonical map  $\mu^{*}(k)\to {\rm Pic}\, G$ (Proposition VII.1.5, p.106). By examining Raynaud's proof, all I can see is that the latter map is an injection whose cokernel is a torsion group annihilated by some power of the characteristic of $k$. So, my question is: has it really been proved in the literature that Sansuc's statement  ${\rm Pic}\, G=\mu^{*}(k)$ is true in positive characteristic even when $\mu$ is not smooth?
 A: I'm not sure if there is really a literature gap, or maybe it is addressed in some reference that just hasn't come to mind. Anyway, let $G$ be a perfect smooth connected affine group over a field $k$, so $G_K$ has no nontrivial $K$-homomorphism to ${\rm{GL}}_1$ for any extension field $K/k$, and hence $K[G]^{\times} = K^{\times}$ by Rosenlicht's Unit Theorem. If $L'$ is a line bundle on ${\rm{Pic}}(G_{k'})$ for a finite Galois extension $k'/k$ such that the isomorphism class of $L'$ is ${\rm{Gal}}(k'/k)$-invariant, it therefore follows via Hilbert 90 that the isomorphisms to the Galois-twists can be arranged to satisfy the cocycle condition, so the natural map
$${\rm{Pic}}(G) \rightarrow {\rm{Pic}}(G_{k'})^{{\rm{Gal}}(k'/k)}$$
is surjective, and hence by passing to the direct limit on such $k'/k$ we see that the natural map
$${\rm{Pic}}(G) \rightarrow {\rm{Pic}}(G_{k_s})^{{\rm{Gal}}(k_s/k)}$$
is surjective.  
But this latter map is also injective. Indeed, again by limit considerations it suffices to show if $L$ is a line bundle on $G$ such that $L_{k'}$ admits a nowhere-vanishing global section $s'$ over $G_{k'}$ for a finite Galois extension $k'/k$ then $L$ admits a nowhere-vanishing global section.  For each $\gamma \in {\rm{Gal}}(k'/k)$, the canonical $\gamma$-equivariant action on $L_{k'}(G_{k'}) = k' \otimes_k L(G)$ satisfies $\gamma(s') = c_{\gamma} s'$ for a unique $c_{\gamma} \in k'[G]^{\times} = {k'}^{\times}$, and $\gamma \mapsto c_{\gamma}$ is a 1-cocycle. Thus, by Hilbert 90 there exists $u' \in {k'}^{\times}$ such that $c_{\gamma} = \gamma(u')/u'$ for all $\gamma$, so $s'/u'$ is a nowhere-vanishing global section that is Galois-invariant and hence corresponds to a trivialization of $L$ over $G$.
Now assume $G$ is a connected semisimple $k$-group. Letting $\widetilde{G} \rightarrow G$ be the simply connected central cover over $k$, with central kernel denoted $\mu$, we have ${\rm{Pic}}(\widetilde{G}) = 1$ by the above injectivity applied to $\widetilde{G}$ because ${\rm{Pic}}(\widetilde{G}_{k_s})=1$.
To see this latter triviality, note that for any split connected reductive group $H$ over a field $F$, the "open cell" relative to a choice of split maximal $F$-torus and Borel $F$-subgroup containing it provides a dense open subscheme that is $F$-isomorphic to a direct product of copies of $\mathbf{A}^1_F$ and $\mathbf{A}^1_F - \{0\}$. Using such an open subscheme enables one to show that the group ${\rm{Pic}}(H)$ is identified with the group of central extensions $E$ of $H$ by ${\rm{GL}}_1$ as $F$-groups by adapting the proof of the Weil-Barsotti formula describing the dual abelian variety in terms of extensions by ${\rm{GL}}_1$ -- see section 4 in the paper "Local Properties of Algebraic Group Actions" by Knop, Kraft, Luna, and Vust for that argument (presented in the setting over algebraically closed fields, but via completely general methods that work for a split connected reductive group over any field). If the $F$-split $H$ is connected semisimple and simply connected then there are no such nontrivial extensions $E$ since necessarily $E$ is connected reductive and hence $\mathscr{D}(E) \rightarrow H$ is a central isogeny (so an isomorphism when $H$ is simply connected). This shows ${\rm{Pic}}(H)=1$ in such cases, so ${\rm{Pic}}(\widetilde{G}_{k_s})=1$ as claimed (and from the consequence ${\rm{Pic}}(\widetilde{G})=1$ we obtain the non-obvious fact that $k[\widetilde{G}]$ is a UFD).
The result VII 1.5 that you refer to in Raynaud's thesis provides an injective homomorphism $\mu^*(k_s) \rightarrow {\rm{Pic}}(G_{k_s})$ (this map assigns to any $k_s$-homomorphism $\chi:\mu_{k_s} \rightarrow {\rm{GL}}_1$ the $\chi$-pushout of the central extension $1 \rightarrow \mu_{k_s} \rightarrow \widetilde{G}_{k_s} \rightarrow G_{k_s} \rightarrow 1$), and it is Galois-equivariant by design. Hence, as long as this is an equality, which is purely a counting question (due to its injectivity), it follows by the preceding arguments that passage to ${\rm{Gal}}(k_s/k)$-invariants gives that the natural map $\mu^*(k) \rightarrow {\rm{Pic}}(G)$ is an equality. In this way, we see that the result asserted without proof in Remark VII 1.7(a) of Raynaud's thesis (basically the affirmative answer to the question posed in the split case) gives the desired result over $k_s$ and hence over $k$. This doesn't answer the question of providing a literature reference with a complete proof, but it "confirms" that a complete proof should have been known to experts in Paris since the 1960's.
