Let me first ask the question for two-dimensional compact, connected manifolds and orbifolds. Then, if the answer is No, one can remove various conditions on the dimension, and allow non-compact examples and disconnected examples, to realize a (perhaps) wider range of rationals.
This came up after a class I'm teaching and I didn't know the answer.
Related:
- MO question "Euler characteristic of orbifolds."
- Wikipedia table for 2-dim orbifolds