a)
Consider the values of your functions $e^{a_1z},...,e^{a_nz}$ at $z=1$.
Lindemann-Weierstrass theorem:
"If $a_1,...,a_n$ are algebraic numbers that are $\mathbb{Q}$-linearly independent, then $e^{a_1},...,e^{a_n}$ are $\mathbb{Q}$-algebraically independent."
With help of Lindemann-Weierstrass theorem, we find that the function values of your functions are $\mathbb{Q}$-algebraically independent at $z=1$. That there exists at least one place where your function values are $\mathbb{Q}$-algebraically independent means that your functions are $\mathbb{Q}$-algebraically independent.
b)
Lang, S.: Introduction to transcendental numbers. Addison-Wesley, 1966, p. 8:
"Let $\beta_1,...,\beta_m$ complex numbers, linearly independent over the rationals. Then the functions
$$e^{\beta_1t},...,e^{\beta_mt}$$
are algebraically independent over the complex numbers."
For $\beta_1,...,\beta_m$ $\mathbb{Q}$-linearly independent algebraic numbers, the prerequisites are met, and your functions are $\mathbb{C}$-algebraically independent.