No. By the Jordan normal form theorem every matrix in $GL(2,{\bf R})$ is conjugate to
either a diagonal matrix $$\left(\begin{array}{cc}\lambda_1&0\\
0&\lambda_2\end{array}\right)$$
(clearly the set of these classes is homeomorphic to $({\bf R}\setminus 0)^2/({\bf Z}/2{\bf Z})$ with ${\bf Z}/2{\bf Z}$ acting by permutation of the two coordinates.)
or to a multiple of a triangular matrix $$\left(\begin{array}{cc}\pm 1&n\\
0&\pm 1\end{array}\right)$$
or to a multiple of a matrix in $SO(2)$.
However, the triangular matrices with eigenvalues $1$ are all in one of three orbits because of
$$\left(\begin{array}{cc}\lambda_1&0\\
0&\lambda_1^{-1}\end{array}\right)\left(\begin{array}{cc}1&n\\
0&1\end{array}\right)\left(\begin{array}{cc}\lambda_1^{-1}&0\\
0&\lambda_1\end{array}\right)=\left(\begin{array}{cc}1&\lambda_1^2n\\
0&1\end{array}\right).$$
The three orbits correspond to the cases $n>0, n=0, n<0$. Note that the orbits for $n>0$ and $n<0$ can not be separated from the identity matrix (the case $n=0$) by any open neighborhood of the identity, because $\lambda_1^2n$ tends to zero for a suitable sequence of $\lambda_1$'s.
So the quotient space is non-Hausdorff, it contains of a copy of $({\bf R}\setminus 0)^2/({\bf Z}/2{\bf Z})$ and another two points which can not be separated from $(1,1)$.