Some divisibility constraints in Frobenius coin problem Let's say that the linear form $ax+by$ represents $n$ if $ax+by=n$ for some positive integer $x$ and $y$. 
Call a pair $(a,b)\in\Bbb N\times\Bbb N$ with $\mathsf{gcd}(a,b)=1$ excellent if linear form $ax+by$ has following property: For each composite $n<(a-1)(b-1)$ (the Frobenius number of $(a,b)$) represented by the linear form there is exactly one collection of divisors starting from some $t_j\geq t_1>a,b$ to $t_s\geq t_j$ at every $i\geq1$ those $t_{i}$ with $t_j|t_{i}$ in $a,b<t_1<\dots<t_s\leq n$ is represented by the linear form and no other divisors are represented.
Do excellent pairs exist at all?
If they do, then is it true that for every sufficiently large integer $l$, there is a excellent pair $(a,b)$ with $a,b\in[l,2l]$?
Note that every excellent pair is a good pair in Problem related to Frobenius coin problem and so excellent pair is a stronger condition.
 A: As I read the question, you want find certain pairs $(a,b)$ to use the linear form $ax+by$ to represent positively only certain numbers, and only in a certain way.  In particular, for any $n$ with $a,b<n<g(a,b)=ab-a-b$, it is either not representable as $ax+by$ for integers $x$ and $y$ where both $x$ and $y$ is at least $1$, or $n$ is representable and at most one of its maximal divisors is also representable.
Well, you aren't going to find many such $a,b$.  Let's pick $s=a+b$.  Then $2s, 3s, 6s$ are also representable, so by your condition $6s \gt ab -a -b$, or $7(a+b)>ab$. So the smaller of $a$ and $b$ is less than $14$, and as $b$ gets large $a$ is bounded above by $7$. And we haven't explored what happens when you pick $\lceil  b/a \rceil a$.  I predict there will be only finitely many such pairs.
Edit 2015.12.02:  I don't see why there is so much difficulty.  I shall attempt a very clear explanation.
Suppose $7(a+b)\leq ab$.  Then $6(a+b) \leq ab -a -b$. Also $6(a+b), 3(a+b)$, and $2(a+b)$ are representable. Thus $(a,b)$ is not an excellent pair.  Thus a pair is excellent implies $7(a+b) \gt ab$, which gives a bound on the smaller of $a$ and $b$, namely if $a$ is smaller then $14 \gt 7(1 + a/b) \gt a$. When $a$ is fixed and not too small $7a/(a-7) \gt b$. The remaining excellent pairs must have the smaller number at most 7.  When the smaller number is 2 or 3, one can choose a larger coprime number to get an excellent pair.  This happens because the interval of representability is too small for the condition to fail.  I leave the cases 4 through 7 to the interested reader.  End Edit 2015.12.02.
Gerhard "Leaving The Rest To You" Paseman, 2015.12.01
