If $X$ is an object in an arbitrary category, there is a natural definition of a subobject of $X$ as a monomorphism into $X$ (or really an equivalence class of monomorphisms). If $X$ is a scheme, however, the term 'subscheme' is conventionally reserved only for locally closed immersions (as in EGA I.4.1.2). There are certainly many monomorphisms of schemes that in this sense aren't subschemes, for example the inclusion of Spec of a local ring such as $Spec K[x]_{(x)} \to Spec K[x]$.
When we restrict 'subscheme' to mean 'locally closed immersion', defining images of schemes becomes problematic. A sensible definition, in any category, of the image of a morphism is the minimal subobject through which it factors. Using the above definition of subscheme, there are perfectly well-behaved examples of morphisms of schemes that don't have images in this sense. For example, consider the morphism $\mathbb A^2_K \to \mathbb A^2_K $ induced by the ring homomorphism $(x,y) \mapsto (x,xy)$; the set-theoretic image is the union of the origin and the complement of the $y$-axis, and there is no minimal locally closed set containing this.
There is, however, always a minimal closed immersion through which a given morphism factors, and so if one defines the scheme-theoretic image in this sense, it always exists. My question is that, if we let our notion of 'subscheme' include all monomorphisms, would the resulting notion of 'scheme-theoretic image' always exist? In other words, is there always a minimal monomorphism of schemes through which a given morphism factors? Say, in the above example? If I hand you a constructible subset of a scheme, can you only find a monomorphism onto that set if it's locally closed?
As a 'softer' question, can someone explain why we don't want to call general monomorphisms subschemes? In particular, suppose I have a morphism that is a submersion onto a locally-but-not-globally closed subscheme. It seems much more sensible to call that locally closed subscheme the image, rather than its global closure.