I know of two good mathematics videos available online, namely:
Do you know of any other good math videos? Share.
Most of the talks at MSRI are videotaped and placed on the web here:
MIT's OpenCourseWare has a few math courses up:
GRASP is a new lecture series at the University of Texas at Austin, which is aimed at bringing some of the fundamental concepts and big picture of the GRASP areas (Geometry, Representation, and Some Physics) to a wider audience (the intended target audience are beginning graduate students).
Along the sphere eversion lines, there is also the energy-minimizing sphere eversion constructed by Rob Kusner. I think there is a video of it at http://www.youtube.com/watch?v=I6cgca4Mmcc, though it isn't labelled as such.
Rob also has written a paper about the history of the minimax eversion.
My personal favorite in Dimensions, that was mentioned before by Gerald Edgar. For a neat and clear exposition the Geom.of 3 manifolds, Poincaré conjecture, etc I recommend this lecture by C.McMullen. Or Das Schöne denken (hosted at the HIM in Bonn), for a good "glimpse in the world of the mathematician". Jos Leys' mathematical imagery contains some (interesting) videos and (a lot of beautiful) images.
I guess all of John Conway's lectures are great. Some of those can be found here : http://www.math.princeton.edu/facultypapers/Conway/
Dror Bar-Natan has begin putting many of his lectures and talks online in video format. I'm not claiming that these are the 'best' online maths videos, but they're certainly interesting, and in particular he's come up with some neat tricks to associate publicly editable annotations with particular moments in the video.
This one is quite old but it was fun when I watched a few years ago. It's about Fermat's Last theorem.
Lots of Lie Theory talks: http://sms.cam.ac.uk/collection/533438?mediaOffset=20&mediaMax=20&mediaOrder=asc&mediaSort=title#Media
John Stillwell - ET Math: How different could it be? A nice talk given at the SETI Institute.
The "Touching Soap Films" series by Springer. about minimal surfaces. Some excerpts of the video are available here: http://page.mi.fu-berlin.de/polthier/video/Touching/Scenes.html
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