Yes, NBG + Equipollence, which is equivalent to NBG + Global Choice, is a conservative extension of ZFC; this was independently discovered by many people (at least Cohen, Felgner, Grishin, Jensen, Kripke, and Solovay). A detailed proof can be found in
Ulrich Felgner: Comparison of the axioms of local and universal choice, Fundamenta Mathematicae 71 (1971), pp. 43–62 (EUDML, PLDML).
The basic idea of the proof is pretty straightforward: you take the class of injective (set) functions whose domain is an initial segment of On as your forcing conditions, and then a generic filter gives you a bijection of On and V. (Actually, Felgner uses choice functions as forcing conditions, but that does not make much of a difference.)
The result is also included in the follow-up surveyish paper
Ulrich Felgner: Choice functions on sets and classes, in Sets and classes: On the work of Paul Bernays (Gert H. Müller, ed.), North-Holland, Amsterdam, 1976, pp. 217–255, doi 10.1016/S0049-237X(08)70895-4.
This paper also discusses a generalization of the result to set theory without the foundation axiom ($\mathrm{ZFC}_-$, $\mathrm{NBG}_-$). It turns out that in absence of foundation, equipollence has nontrivial consequences even for sets: $\mathrm{NBG}_- + \mathrm{Equipollence}$ is a conservative extension of $\mathrm{ZF}_-$ extended by the schema
$$\forall x\:\exists y\:\phi(x,y)\to\forall\alpha\in\mathrm{On}\:\exists f\colon\alpha\to\mathrm{V}\:\forall\beta<\alpha\:\phi(f\restriction\beta,f(\beta))$$
(a sort of class version of $\mathrm{DC}_\alpha$; an equivalent formulation: any class tree whose height is bounded by an ordinal has a maximal path). This schema implies AC and collection (assuming replacement), but one can show that it is strictly stronger than that (i.e., independent of $\mathrm{ZFC}_- + \mathrm{Collection}$).
Note that without foundation, equipollence still implies global choice, but not vice versa. It is apparently an open problem if $\mathrm{NBG}_- + \mathrm{Global\ Choice}$ is conservative over $\mathrm{ZFC}_-$.