Let $S$ be a Coxeter diagram, i.e. an unoriented graph, edges labelled by weights $3,4,5,...$ . This includes (affine) Dynkin diagrams,
Then
Theorem 3.1.3 of Brouwer and Haemers' Spectral Graph Theory says that the only graphs $\Gamma$ whose adjacency matrix $A_\Gamma$ has largest eigenvalue (less than) $2$ are the affine (resp. ordinary) ADE diagrams.
Now, the Coxeter group $W_S$ of the diagram always acts on the vector space $\text{Fun}(S)\simeq\mathbf{C}^{|S|}$ of functions on the graph. Does this action commute with taking $A_S$, and if so do we know anything about how the $A_S$-eigenspaces decompose as representations of $W_S$?
Or more generally - is there any other interesting connection between Coxeter groups/root systems/etc. and eigenvalues of the Laplacian? The purpose of this question is to understand if the above Theorem is a cute coincidence or whether there is more structure here to understand.