The Poincaré polynomial of $G/P$ in general is $\sum_w q^{\ell(w)}$ where the sum is over all minimal length coset representatives of $W_G/W_P$ (here $W_G$ is the Weyl group of $G$ and $W_P$ is the Weyl group of the Levi factor of $P$). $q$ is an element of degree 2. I don't know who originally proved this, but it is contained in Section 5 of one of the papers of BGG: https://iopscience.iop.org/article/10.1070/RM1973v028n03ABEH001557/meta
This sum has a very simple formula as a quotient: let $d_1,\dots,d_n$ be the degrees of the basic invariants for $G$ and let $e_1,\dots,e_m$ be those for the Levi subgroup. Then the formula is $\displaystyle \frac{[d_1]\cdots [d_n]}{[e_1]\cdots [e_m]}$ where I use the notation $[p] = (1-q^p)/(1-q)$.
If we apply this to $P$ being the parabolic that preserves the highest root of the adjoint representation here are the formulas for simple groups (I hope I did not make any mistakes):
$SL_{n+1}$: $[n][n+1]$
$SO_{2n+1}$: $\displaystyle \frac{[2n-2][2n]}{[2]}$
$Sp_{2n}$: $[2n]$
$SO_{2n}$: $\displaystyle \frac{[2n-4][2n-2][n]}{[n-2][2]}$
$E_6$: $\displaystyle \frac{[8][9][12]}{[3][4]}$
$E_7$: $\displaystyle \frac{[12][14][18]}{[4][6]}$
$E_8$: $\displaystyle \frac{[20][24][30]}{[6][10]}$
$F_4$: $\displaystyle \frac{[8][12]}{[4]}$
$G_2$: $[6]$