The equality $D_p = C_p$ holds for compact symmetric spaces (CROSSes) of rank $1$, but not in general for higher rank symmetric spaces.
A rank $1$ CROSS is isometric to a round sphere or projective space with Fubini-Study metric. For a sphere, we of course have $D_p = C_p = \{-p\}$. On $\mathbb{K}P^n$ with $\mathbb{K}\in\{\mathbb{R},\mathbb{C},\mathbb{H},\mathbb{O}\}$, we have $D_p = C_p \cong \mathbb{K}P^{n-1}$.
For higher rank, consider $Sp(n)$ (the $n\times n$ quaternionic unitary matrices) with bi-invariant metric and set $p = I$, the identity matrix.
We claim that $D_p = \{-I\}$. Indeed, given $q\in D_p$, we may select a minimizing geodesic $\gamma$ from $p$ to $q$. This geodesic is a $1$-parameter subgroup, so can be conjugated to lie within the standard maximal torus $T^n\subseteq Sp(n)$. On the torus (which inherits its standard flat metric) clearly $-I$ is the farthest point from $I$. So, $q$ is conjugate to $-I$, which is central.
On the other hand $C_p$ contains infinitely many points. To see this, recall that $Sp(n)\setminus \{p\}$ deformation retracts onto $C_p$. This implies that in cohomology we have $H^3(C_p)\neq 0$ for $n\geq 2$