There is no need to use the subscript $4$ on the $L$-function: just write
$L(s,\chi_4)$ and $L^*(s,\chi_4)$. The first nontrivial zero in the upper half of the critical strip is $1/2 + it$ where
$t \approx 6.020948i$.
Data for $L(s,\chi_4)$ is available on the LMFDB: see https://www.lmfdb.org/L/1/2e2/4.3/r1/0/0. You can find imaginary parts of the initial zeros in the upper and lower half-plane towards the bottom of the page (the zeros are symmetric since $\chi_4$ is quadratic).
In PARI, the command lfunzeros(L,T) computes imaginary parts $t$ of critical zeros with "$L$" being some $L$-function data (datum?) and $0 \leq t \leq T$. Being lazy, let's take L to be $x^2+1$, whose $L$-function is the zeta-function of $\mathbf Q(i)$, namely $\zeta(s)L(s,\chi_4)$. Typing lfunzeros(x^2+1,20), I get the answer
[6.0209489046975966549025115216120858689, 10.243770304166554552137757479109959025, 12.988098012312422507453109789562993765, 14.134725141734693790457251983562470271, 16.342607104587222194976861483456149939, 18.291993196123534838526004277590699428].
Only 14.1347... belongs to $\zeta(s)$; the rest are zeros of $L(s,\chi_4)$.
See https://pari.math.u-bordeaux.fr/pub/pari/manuals/2.13.3/refcard-lfun.pdf for a printout listing PARI 𝐿-function commands and https://pari.math.u-bordeaux.fr/dochtml/html-stable/_L_minusfunctions.html for a similar webpage.