As for the second question, the equivalence relation on the class of countable ICC groups given by $G \sim \Gamma$ if and only if $L(G) \cong L(\Gamma)$ is very interesting and usually called $W^*$-equivalence of $G$ and $\Gamma$.
On page 45 of [Con82], Connes conjectures that the $W^*$-equivalence class of an ICC property (T) group is a singleton (up to isomorphism). Such groups are now called $W^*$-superrigid. This conjecture is wide open. At the moment, there is no counterexample, but also no example: there is no known $W^*$-superrigid property (T) group.
In Section 4 of [Pop07] it is proven that an ICC property (T) group is $W^*$-equivalent with at most countably many nonisomorphic groups.
In [IPV10] we introduced the first family $W^*$-superrigid ICC groups. These examples are given by a generalized wreath product construction and do not have property (T).
For all countably infinite abelian groups $\Gamma$, the group von Neumann algebra $L(\Gamma)$ is the unique diffuse abelian von Neumann algebra. One can deduce that for all countably infinite abelian groups $\Gamma_1,\Gamma_2$, the ICC group $\Gamma_1 * \Gamma_2$ is $W^*$-equivalent to the free group $\mathbb{F}_2$. More generally, by Theorem 4.6 in [Dyk92], whenever $\Gamma_1$ and $\Gamma_2$ are infinite amenable groups, we have that their free product $\Gamma_1 * \Gamma_2$ is $W^*$-equivalent to $\mathbb{F}_2$.
[Con82] A. Connes, Classification des facteurs. In Operator algebras and applications, Part 2 (Kingston, 1980), Proc. Sympos. Pure Math. 38, Amer. Math. Soc., Providence, 1982, pp. 43–109.
[Pop07] S. Popa, Deformation and rigidity for group actions and von Neumann algebras. In International Congress of Mathematicians (Madrid 2006), Eur. Math. Soc., Zürich, 2007, pp. 445-477.
[IPV10] A. Ioana, S. Popa and S. Vaes, A class of superrigid group von Neumann algebras. Ann. of Math. 178 (2013), 231-286.
[Dyk92] K. Dykema, Free products of hyperfinite von Neumann algebras and free dimension. Duke Math. J. 69 (1993), 97–119.