$\newcommand{\Om}{\Omega}
\newcommand{\F}{\mathcal{F}}$Prompted by a comment by Nate Eldredge, I found this in Wikipedia :
For any $0<r<p$ the expression
$$\||f|\|_{L^{p,\infty}}=\sup_{0<\mu(E)<\infty}\mu(E)^{-1/r+1/p}\Big(\int_E
|f|^r\,d\mu\Big)^{1/r}$$
is comparable to the $L^{p,w}$-norm.
Taking here $r=1$ and $p=2$, we conclude that
$\mathcal F$ is the weak $L^2$ space $L^{2,w}$.
Let us also provide a direct proof of the latter statement. Recall that
\begin{equation*}
L^{2,w}=\Big\{f\in L^0(\Om)\colon\;\exists C\in(0,\infty)\ \forall t\in(0,\infty)\ P_f(t)\le C/t^2\Big\},
\end{equation*}
where $$P_f(t):=\big|[|f|>t]\big|$$ and $[|f|>t]:=\{x\in\Om\colon|f(x)|>t\}$.
On the other hand, as was shown in my other answer on this web page,
\begin{equation*}
\F=\Big\{f\in L^1(\Om)\colon\;\exists C\in(0,\infty)\ \forall t\in(0,\infty)\,\int_{[|f|>t]}|f|\le C\sqrt{P_f(t)}\Big\}. \tag{0}
\end{equation*}
Take any $f\in L^0(\Om)$ and any $t\in(0,\infty)$. Then
\begin{align*}
\int_{[|f|>t]}|f|&=\int_\Om 1_{[|f|>t]}\,|f| \\
&=\int_\Om 1_{[|f|>t]}\int_0^\infty ds\,1_{[|f|>s]} \\
&=\int_0^\infty ds\,\int_\Om 1_{[|f|>t]}1_{[|f|>s]} \\
&=\int_0^t ds\,\int_\Om 1_{[|f|>t]}
+ \int_t^\infty ds\,\int_\Om 1_{[|f|>s]} \\
&=tP_f(t) + \int_t^\infty ds\,P_f(s). \tag{1}
\end{align*}
If now $f\in\F$ then, by (1),
\begin{equation*}
tP_f(t)\le \int_{[|f|>t]}|f|\le C\sqrt{P_f(t)},
\end{equation*}
so that $P_f(t)\le C^2/t^2$ and hence $f\in L^{2,w}$. Thus,
\begin{equation*}
\F\subseteq L^{2,w}. \tag{2}
\end{equation*}
To prove that $\F\supseteq L^{2,w}$, take any $f\in L^{2,w}$, so that
\begin{equation*}
P(t):=P_f(t)\le C/t^2 \tag{3}
\end{equation*}
for some real $C>0$ and all real $t>0$. The function $P$ is nonincreasing and right-continuous on $(0,\infty)$, with $P(\infty-)=0$. Consider the generalized inverse $P^{-1}$ of $P$ given by the formula
\begin{equation*}
t_u:=P^{-1}(u):=\inf\{s\ge0\colon P(s)\le u\}=\min\{s\ge0\colon P(s)\le u\}
\end{equation*}
for $u\in(0,P(0))$. Then for all real $s\ge0$ and all $u\in(0,P(0))$ we have
\begin{equation*}
s<t_u\iff u<P(s). \tag{4}
\end{equation*}
So, for any real $t>0$
\begin{align*}
\int_t^\infty ds\,P_f(s)&=\int_t^\infty ds\,\int_0^{P(s)}du \\
&=\int_0^{P(t)}du \int_t^{t_u} ds\,\\
&=\int_0^{P(t)}du\, (t_u-t)\,\\
&\le\int_0^{P(t)}du\,t_u.
\end{align*}
By (3), for any real $u>0$ we have $P(\sqrt{C/u})\le u$, whence, by (4), $t_u\le\sqrt{C/u}$. Now the latter multi-line display yields
\begin{equation*}
\int_t^\infty ds\,P_f(s)\le2\sqrt C\,\sqrt{P_f(t)}.
\end{equation*}
Also, (3) is obviously equivalent to $tP_f(t)\le\sqrt C\,\sqrt{P_f(t)}$.
So, by (1),
\begin{align*}
\int_{[|f|>t]}|f|\le3\sqrt C\,\sqrt{P_f(t)},
\end{align*}
so that, by (0), $f\in\F$.
Thus, indeed $\F\supseteq L^{2,w}$. Now (2) yields
\begin{equation*}
\F=L^{2,w},
\end{equation*}
as claimed.