An elementary proof.
From
\begin{equation}
\arcsin x=\sum_{\ell=0}^{\infty}\frac{1}{2^{2\ell}}\binom{2\ell}{\ell}\frac{x^{2\ell+1}}{2\ell+1}, \quad |x|<1,
\end{equation}
it follows that
\begin{equation*}
\frac{1}{2}\arcsin(2x)=\sum_{k=0}^{\infty}\frac{1}{2k+1}\binom{2k}{k}x^{2k+1},\quad |x|<\frac{1}{2}
\end{equation*}
and, by differentiation,
\begin{equation*}
\frac{1}{\sqrt{1-4x^2}\,}=\sum_{k=0}^{\infty}\binom{2k}{k}x^{2k},\quad |x|<\frac{1}{2}.
\end{equation*}
Squaring on both sides, using the geometric series expansion, and utilzing the Cauchy product of the multiplication of two power series yield
\begin{equation*}
\sum_{k=0}^\infty2^{2k}x^{2k}=\frac{1}{1-4x^2}=\Biggl[\sum_{k=0}^{\infty}\binom{2k}{k}x^{2k}\Biggr]^2
=\sum_{k=0}^\infty\Biggl[\sum_{i=0}^k\binom{2i}{i}\binom{2(k-i)}{k-i}\Biggr]x^{2k}, \quad |x|<\frac{1}{2}.
\end{equation*}
Equating the coefficients of $x^{2k}$ results in
$$
\sum_{i=0}^k\binom{2i}{i}\binom{2(k-i)}{k-i}
=\sum_{i+j=k}\binom{2i}{i}\binom{2j}{j}
=2^{2k}, \quad k\ge0.
$$
The idea of this elementary proof comes from the following paper
Feng Qi, Chao-Ping Chen, and Dongkyu Lim, Several identities containing central binomial coefficients and derived from series expansions of powers of the arcsine function, Results in Nonlinear Analysis 4 (2021), no. 1, 57--64; available online at https://doi.org/10.53006/rna.867047.
This elementary proof is simpler than the proof of Theorem 3.4 on page 232 in the following paper
Necdet Batır, Hakan Küçük, and Sezer Sorgun, Convolution identities involving the central binomial coefficients and Catalan numbers, Transactions on Combinatorics 10 (2021), no. 4, 225--238; available online at https://dx.doi.org/10.22108/toc.2021.127505.1821.