Here is a rather revised answer. I originally thought that having a line of symmetry (bisecting one or perhaps two edges ) might be a sufficient condition. Joseph showed a convincing counter-example to my reasoning. And Alexandre's observations finished it off.
Here is what I can salvage and add.
I'm not so interested in non-polygonal paths but here are a few
1) On the left below is a variation of the right triangle construction showing that a convex (or simply not too badly reentrant) polygonal table with a right angle has a simple periodic billiard path of the form $abcdcba.$ There are arbitrary further sides not shown.
One might require that a path touch all the sides in order to avoid arbitrary modifications which don't affect the path.
2) The top middle diagram is an isosceles triangle table with a path $bacab$ and another $defgfed.$
I'll now restrict to polygons with a simple periodic polygonal billiards path touching each side.
3) A construction given for (acute) isosceles triangle applies to arbitrary acute triangles. Drop the perpendicular from each vertex to the opposite sides. There is a path touching at just those points.
As Alexandre showed, any convex polygon can be a path and the path determines the polygonal table up to similarity (if we require equal number of sides. Will pointed if the path has angles $\alpha_1,\alpha_2,\cdots,\alpha_n$ then the table has angles $\frac{\alpha_i+\alpha_{i+1}}2.$ This provides a necessary condition for a table to have a path. It is a sufficient condition for a circularly ordered lists of angles to be realized by some tables having a path.
4) For a triangular path the table will have angles $\frac{\pi-\alpha_1}2,\frac{\pi-\alpha_2}2,\frac{\pi-\alpha_3}2.$ Hence an obtuse or even a right triangle has no triangular paths. This tells us everything about triangular tables.
5) For quadrilateral tables we see that opposite angles must add to $\pi.$ That is a strong condition (strong enough to demolish my conjecture.) However I have drawn a quadrilateral below with angles $\frac{\pi}4,\frac{\pi}2,\frac{3\pi}4,\frac{\pi}2.$ It is only slightly modified from a right triangle with no path. Since the angles are rational it should be possible to determine if it has a quadrilateral path. But I doubt it does.
6) Regular polygons have polygonal paths. The final table is pentagonal with all angles $\frac{3\pi}5.$ It even has a central line of symmetry. However I again suspect that it does not have a path of the type we seek.