You can prove that such threefolds are either P^1-fibration over a base,
which is a surface with $h^{2,0}=1$, or have pseudoeffective canonical
bundle: arXiv:1304.7891, Corollary 4.3. In the later case you can run the
minimal model program, obtaining that your variety is either general type or
is a (singular) fibration with Calabi-Yau fibers over a general type
variety with canonical singularities. However, since $h^{2,0}=1$, your
base has $h^{2,0}<2$, and this restriction is pretty strong: either
you have an elliptic fibration over a surface, or a K3 or toric
fibration over an elliptic curve.