The prime motivation to introduce the category of manifolds with corners is to have a convenient theory for the analysis on simplices that is as powerful as for smooth manifolds (with boundaries).
As far as I understand, polygonally bounded subdomains of $\mathbb R^n$ are not submanifolds with corners in general, at least for two reasons: (i) The category of manifolds with corners does not include "inward corners" (ii) The number of polygonal boundary pieces that meet at a common point can be arbitrarly large.
Is there a category of manifolds which contains arbitrary polygonal domains (where the boundary pieces may be curved)?