I'm not sure if you're looking only for examples where checking properness/separatedness/etc. is easier using valuative criteria; this is an example where proving something is made easier. The example is liftability of arcs under proper birational morphisms.
A bit of setup: Say $X$ is a variety over a field $k$; an arc $\gamma$ on $X$ is a morphism $\gamma: \mathrm{Spec}\, k[[t]] \to X$. Write $X_\infty$ for the set of arcs on $X$ (in fact, $X_\infty$ carries a natural scheme structure, but we ignore this). The set of arcs on $X$ carries a great deal of information about the singularities of $X$, so it's of interest in birational geometry to understand how sets of arcs behave under proper birational maps; in particular, given $f:Y\to X$ a proper birational map, we want to know what the relation between $Y_\infty$ and $X_\infty$ is. Say that $f$ is an isomorphism over $X-Z$ for some closed subset $Z$ of $X$. "Most" arcs on $X$ don't have scheme-theoretic image contained in $Z_\infty$ (i.e., the morphism $\mathrm{Spec}\, k[[t]] \to X$ doesn't factor through $Z$). Write $Z_\infty$ for the set of arcs on $X$ that do factor through $Z$, and likewise $(f^{-1}(Z))_\infty$ for the arcs on $Y$ factoring through the (set-theoretic) preimage $f^{-1}(Z)$.
We claim that the proper birational morphism $f:Y\to X$ induces a bijection between $Y_\infty-(f^{-1}(Z))_\infty$ and $X_\infty-Z_\infty$, which should be thought of as a bijection away from a "measure zero" set. Using the valuative criterion for properness though, this is super easy to see: take $\gamma $ in $X_\infty-Z_\infty$. Since $\gamma$ is not in $Z_\infty$ the image of the generic point $ \mathrm{Spec}\, k((t)) \to \mathrm{Spec}\, k[[t]] \to X$ lies in the locus where $f$ is an isomorphism, so we can lift $\mathrm{Spec}\, k((t)) \to X$ to a map $ \mathrm{Spec}\, k((t)) \to Y$, giving a diagram
$\require{AMScd}$
\begin{CD}
\mathrm{Spec}\, k((t)) @>>> Y\\
@V V V @VV f V\\
\mathrm{Spec}\, k[[t]] @>>> X
\end{CD}
Now, the valuative criterion for properness of $f$ says exactly that there is a unique lift of $\gamma$ to an arc $\mathrm{Spec}\, k[[t]] \to Y$, giving the desired bijection.
Without using the valuative criterion, the other way I can think to prove this is to recognize $f:Y\to X$ as the blowup of $X$ at some ideal sheaf, and then work locally with the natural charts on the blowup; this isn't hard, but involves involves using the nontrivial fact that all proper birational maps are blowups of some ideal.