By the Schur-Horn inequality I am thinking of the statement that for any Hermitian matrix $H$ its diagonal n-tuple $(H_{11},H_{22},..,H_{nn})$ for any choice of basis lies in the convex hull of the $n!$ permutations of its eigenvalue n-tuple.
Or any further improvement if one assumes not just the p.s.d structure but also that, $H_{ii} = \sum_{j \neq i} H_{ij}$?