I think I’ve once been told that under the Beilinson-Bernstein correspondence, finite-dimensional representations of a semisimple Lie algebra $\mathfrak{g}$ correspond to (twisted) D-modules on $G/B$ whose associated variety in $T^*G/B$ is the zero-section. Similarly, category O modules correspond to (twisted) D-modules microsupported on the union of conormal bundles to Schubert cells.
Can anyone point me to a reference for this?