I suppose the intended inequality is
$$
\left| \frac{m}{n} - |u+v| \, \right| < \left| \frac{m}{n} - |u'+v'| \, \right|
$$
as Wlodzimierz Holsztynski suggests. But
there are no such $m,n$. Indeed for any real $r>0$,
rational or not, there exists a unique element of
$$
U + U := \{ u_1 + u_2 \mid u_1,u_2 \in U \}
$$
closest to $r$.
Proof: If $r\in U$ then $r \in U+U$, because
$r = \frac1n = \frac1{2n} + \frac1{2n}$.
If not, choose $n$ such that
$|r| \geq 1/n$. Then if $u_1,u_2 \in U$ with
$|r - (u_1+u_2)| < \left|r - \frac1n\right|$ then at least one of $u_1,u_2$
exceeds $\frac1{2n}$; without loss of generality assume it is $u_1$.
Then there are finitely many candidates for $u_1$, and for each of them
there is an optimal choice of $u_2$ (because $r \neq u_1$ by hypothesis).
The optimal approximation is then the best one of these as $u_1$ varies over
the finite list of fractions larger than $1/2n$.