I am looking for models of ${\mathsf{Top}}$ distinct from modifications of simplicial sets. The above question should be understandable to the reader. I'll add more details when I get access to a proper computer. Let ${\mathsf{Met}}$ be the category of metric spaces and continuous maps. Then there is an embedding ${\mathsf{Met}}\hookrightarrow {\mathsf{Top}}$. Is this embedding a Quillen equivalence?
Edit: Professor May explains below that my question is not precise, per se, as there is more than one Quillen inequivalent model categorial structures on ${\mathsf{Top}}$.
Edit: The answer is no. Tom commented that the category ${\mathsf{Met}}$ does not have all small colimits. Thus the embedding ${\mathsf{Met}}\hookrightarrow {\mathsf{Top}}$ cannot be a Quillen equivalence.