Following EGA IV, we can construct the sheaf of principal parts of a sheaf $\mathcal{E}$ over a scheme $X$ by $\mathcal{P}_X^n(\mathcal{E}) = \mathcal{P}_X^n \otimes \mathcal{E}$, where $\otimes$ is at the right structure of $\mathcal{P}_X^n$. If $X$ is non-singular and $\mathcal{E}$ is coherent, I can see that $\mathcal{P}_X^n(\mathcal{E})$ is also coherent.
We can put a structure of $\mathcal{O}_X$-module at $\mathcal{Diff}_X^{\le n}(\mathcal{E}, \mathcal{O}_X)$ using the isomorphism of additive group sheaves $\mathcal{Diff}_X^{\le n}(\mathcal{E}, \mathcal{O}_X) \simeq \mathcal{Hom}(\mathcal{P}_X^n(\mathcal{E}), \mathcal{O}_X)$. If $\mathcal{E}$ is coherent, then $\mathcal{Diff}_X^{\le n}(\mathcal{E}, \mathcal{O}_X)$ is reflexive.
Under what conditions $\mathcal{P}_X^n(\mathcal{E})$ is also reflexive? That is, when $\mathcal{P}_X^n(\mathcal{E}) = \mathcal{Hom}(\mathcal{Diff}_X^{\le n}(\mathcal{E}, \mathcal{O}_X),\mathcal{O}_X)$? I can see this under strong assumptions, such as $\mathcal{E}$ locally free, but I expect this to be true under weaker ones(maybe $\mathcal{E}$ reflexive?).
Thanks in advance.