Even Moremore, on the topological manifold $\mathbb{R}^{4}$ it is possible to define uncountably many inequivalent PL or differentiable structures. An excellent account of this exotic $\mathbb{R}^{4}$'s can be found in Chapter XIV of [Kir1989].
- [TOP & DIFF] As John Klein points out in the comments, smoothing a topological manifold is in general a question formulated by first putting a combinatorial structure on the manifold (normally a handlebody structure or a PL structure). The examples of KervaireThat is, Ells & Kuiper$$\mathrm{DIFF}\rightarrow \mathrm{TOP}$$ is nothing but the composition of the previous two functors and Tamura mentioned above yield topological manifolds having no differentiable structure. However, these are still PL manifoldsis therefore neither surjective nor injective.
Indeed, the examples of Kervaire, Ells & Kuiper and Tamura mentioned above yield topological manifolds having no differentiable structure. However, these are still PL manifolds.
The exotic $\mathbb{R}^{4}$'s mentioned earlier give an example of a topological manifold having uncountably many inequivalent differentiable structures. Another example given above are Milnor's non-diffeomorphic $S^{7}$ spheres.