Every flag manifold $M=G^{\mathbb{C}}/P=G/C(S)$ where $P$ is a parabolikparabolic subgroup and $C(S)=P\cap G$ is the centralizer of a torus $S\subset G$, admits a finite number of invariant KahlerKähler structures. In particular the complex presentation $G^{\mathbb{C}}/P$ gives rise to an finite number of invariant complex structures (i.e. integrable almost complex structures commuting with the isotropy representation of $M$). Any such complex structure is determined by an invariant ordering $R_{M}^{+}$ on the set of complementary roots $R_{M}=R\backslash R_{K}$ of $M$ and explicitly is given by $$ J_{o}E_{\pm \alpha}=\pm i E_{\pm\alpha}, \quad a\in R_{M}^{+} $$ where $E_{\alpha}$ are root vectors with respect a Weyl basis of $\frak{g}^{\mathbb{C}}$.
On the other hand, the real presentation $G/C(S)$ makes $M$ a (homogeneous) KahlerKähler manifold, as a (co)-adjoint orbit of an element $w\in\frak{g}$ in the Lie algebra $\frak{g}$ of the compact connected (semi)simple Lie group. Flag manifolds exhaust all compact homgeneous Kahlerhomogeneous Kähler manifolds corresponding to a compact connected semi-simple Lie group.
To be more specific, $M$ admits a finite number of KahlerKähler structures which are parametrized by the well-known $\frak{t}$-chambers (connected components of the set of regular elements of $\frak{t}$) where
$$ {\frak{t}} =( H\in{\frak{h}} : (H, \Pi_{0})=0 ) $$
is a real form of the center ${\frak{z}}$ of the isotropy subgroup $K=C(S)$.
Here $\frak{h}$ is the Cartan subalgebra corresponding to a maximal torus $T$ of $G$ which contains $S$, and $\Pi_{0}\subset\Pi$ is the subgroup of simple roots which define (the semi-simple part of) the complexification $\frak{k}^{\mathbb{C}}$ (note that $K=C(S)=P\cap G$ is areductivea reductive Lie group). We have
$$ {\frak{z}}^{\mathbb{C}}={\frak{t}}\oplus i {\frak{t}}, \ \ \ {\frak{k}}^{\mathbb{C}}={\frak{z}}^{\mathbb{C}}\oplus{\frak{k}}_{ss}^{\mathbb{C}} $$
where ${\frak{z}}^{\mathbb{C}}$ is the complexification of the center ${\frak{z}}$ and ${\frak{k}}_{ss}^{\mathbb{C}}$ is the semi-simple part of the reductive complex Lie subalgebra ${\frak{k}}^{\mathbb{C}}$
In particular, there exists a natural 1-1 corespondencecorrespondence between elements from ${\frak{t}}$ and closed invariant 2-forms on $M$. Symplectic 2-forms (non-degenerate) correspond to regular elements $t$ of ${\frak{t}}$.
Note that the corresponding symplectic form corresponding to a regular elemntelement $t_{0}$ is the Kirillov-Kostant-Souriau 2-form in the (co)-adjoint orbit $Ad(G)t_{0}$, that is
$$ \omega_{t_{0}}(X, Y)=B(t_{0}, [X, Y]), \ \ X, Y\in T_{t_{0}}M. $$
For more details see: D. Alekseevsky: Flag manifolds (11. Yugoslav Geometrical seminar, Divcibare, 10-17 October 1993, 3-35. This article is a very good review on the geometry of flag manifolds.