For the classical Lie groups, I think that an easy way to obtain the result is through the fibrations:
SO(n-1)-->SO(n)--> $S^{n-1}$$SO(n-1)\to SO(n)\to S^{n-1}$,
SU(n-1)-->SU(n)--> $S^{2n-1}$$SU(n-1)\to SU(n)\to S^{2n-1}$,
SP(n-1)-->SP(n)--> $S^{4n-1}$$SP(n-1)\to SP(n)\to S^{4n-1}$
and the homotopy long exact sequence and pi_m(S^n) = 0$\pi_m(S^n) = 0$ for m$m$ less than n$n$, and pi_2(SO(2)) = pi_2(SU(2)=0$\pi_2(SO(2)) = \pi_2(SU(2))=0$ and the isomorphism of SP(2)$SP(2)$ and SO(5)$SO(5)$.