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Dec 30, 2011 at 17:47 comment added Ian Agol I think Schlafli's formula for 4-D hyperbolic simplices actually gives an affine function of the sum of the dihedral angles, since the volume of the codim 2 faces is always $\pi$. But I'm not sure how one uses this to deduce the regular ideal 4-simplex is maximal volume, since as you say, the moduli space of dihedral angles is complicated.
Dec 29, 2011 at 20:57 comment added John Pardon Oops, looks like I'm too focused on $n=3$ and have forgotten that things might be different in higher dimensions . . . I've edited the question which now hopefully gives a more accurate picture.
Dec 29, 2011 at 19:23 history answered Igor Rivin CC BY-SA 3.0