Given a unitary matrix $A$ with entries $a_{ii}$, it's clear that the matrix $B$ with entries $b_{ii} = |a_{ii}|^2$ is doubly stochastic. Is the inverse of this statement true? Namely, given a doubly stochastic matrix $B'$ with entries $\beta_{ii}$, does there exist a unitary matrix with entries $\alpha_{ii}$ such that $|\alpha|^2_{ii} = \beta_{ii}$?