The doubled manifold is only a (piecewise smooth) $C^0$-manifold, unless you put more structure on the initial manifold with boundary.
In dimension one, then you get a little bit more: you get a $C^1$-structure on the double.
But still, you do not get a $C^2$-structure.
Here's how it goes:
Take $\mathbb R_+$ with its standard smooth structure.
Its double is $\mathbb R$.
Now let's analyze this further:
If you want that construction to be functorial (w.r.t diffeomorphisms), then you would like the diffeomorphism group of $\mathbb R_+$ to act on $\mathbb R$.
In other words, you want a group homomorphisms
$$
Di\\!f\\!f(\mathbb R_+) \longrightarrow Di\\!f\\!f(\mathbb R),\qquad \varphi\mapsto\bar\varphi,
$$$$
Di\!f\!f(\mathbb R_+) \longrightarrow Di\!f\!f(\mathbb R),\qquad \varphi\mapsto\bar\varphi,
$$
where $\bar\varphi$ is defined by $\bar\varphi(x):=\varphi(x)$ for positive $x$, and
$\bar\varphi(x):=-\varphi(-x)$ for negative $x$.
Now take $\varphi(x):=x+x^2$. One easily checks that $\bar\varphi$ is not $C^2$!
$\qquad$ Conclusion:
$\qquad$ the double of $\mathbb R_+$ is only equipped with a canonical $C^1$ structure.
$\qquad$ It does NOT have a canonical $C^2$ structure.
Note: The same argument as above with $\mathbb R\times \mathbb R_+$, and the map
$\varphi(x,y):=(x+y,y)$ shows that the double of $\mathbb R\times \mathbb R_+$ is not $C^1$.
On the positive side, here are two situations where it is possible to equip the double with a canonical smooth strucutre:
if your manifold is Riemannian structure, and the boundary totally is geodesic.
in two dimensions, a complex structure induces a smooth structure on the double.
(no compatibility required between the cx structure and the boundary)