ADDED: One might worry about whether in general, a solution obtained as indicated above is the correct one. For instance, in the example with $\alpha = 1/5$, the equation $x^2 = (x^5+1)/2$ has, apart from the three real roots, also two non-real roots, and even after finding a solution $f$ involving only the two real roots other than 1, it might not be totally obvious that there is no other real function of the form $g(n) = A_1x_1^n+\cdots+A_5x_5^n$ that satisfies the boundary conditions (this would be possible if the two non-real roots had absolute value smaller than 1).
There is a simple application of Brownian motion that shows that anything that satisfies the recursion $g(n+2) = (g(n) + g(n+5))/2$ as well as the boundary conditions, must be the correct solution. I picked this up recently from Jeff Steif (in a slightly different context), who told me he heard it from Yuval Peres twenty years ago. Here is how it goes:
Suppose that someone gives us a function $g$ that satisfies $g(-1) = g(-2) = 1$, $g(n+2) = (g(n) + g(n+5))/2$ for $n\geq 0$, and $g(n)\to 0$ as $n\to\infty$. Since such a function must have the form $A_1x_1^n+\cdots+A_5x_5^n$, it is easy to see that all the values have to be in the interval $[0,1]$ (there could not be a smallest value of $g$).
Now start a Brownian motion on the real line from the point $g(0)$, and run it until it hits either $g(-2)$ or $g(3)$. If it hit $g(3)$, continue until it hits $g(1)$ or $g(6)$, etc. In finite time, the particle will reach either $1=g(-1) = g(-2)$ or 0 (in case it went through $g(n)$ for some sequence of $n$'s tending to infinity).
It follows from basic properties of the Brownian motion that the probability that it reaches 1 before reaching zero is $g(0)$. Since the process correctly emulates the discrete random walk of steps $+3$ and $-2$, it follows that the probability that the emulated walk on the integers reaches $-1$ or $-2$ before going to infinity is also $g(0)$.
Therefore the boundary conditions uniquely specify the solution (and the argument obviously generalizes to any rational $\alpha$).