Re 2, for $n=1$, $P_{ij}=f^1_{ij}$ for every $i\ne j$ and $P_{ii}=1-\displaystyle\sum_{j\ne i}f^1_{ij}$$1-P_{ii}$ is the sum of $f^1_{ij}$ over $j\ne i$, hence one recovers trivially $P$ from $f^1$$f^1=(f^1_{ij})_{ij}$. On
Re 2 again, on the contrary, there is no hope to recover $P$ from $f^n$$f^n=(f^n_{ij})_{ij}$ in general, for any given $n\ge2$. For example, the two (deterministic) one-step rotations on the discrete circle with $(2n)$$2n$ vertices, clockwise and counterclockwide, yield the same matrix $f^n$ although their transition matrices $P$ are different if $n\ge2$.