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Sep 4 at 14:51 history bounty ended ACR
Aug 29 at 13:36 comment added ACR Very useful analysis. I think you are right and your reasoning also resonates with the software author. We are already in a good region by good guesses. In practice the experimental peak functions in a chromatogram are fitted with respect to x (time) starting from 0 to some time t? Could this be another reason, among others, for the 30 year old robustness of the Levenberg-Marquardt method as claimed by the software author? He said, he never had a problem.
Aug 28 at 14:16 history answered Martin Modrák CC BY-SA 4.0