Hopf algebras are special case of cogroups in the category of unital rings.
In $(hTop_*,\vee)$ (Pointed topological spaces with maps between homotopy classes of pointed continuous maps, and $\vee$ the smash product), the spheres $S^n$ with a fixed points are cogroups. The counit $S^n \rightarrow *$ being the terminal map, the coinverse is the symmetry with the equator $S^{n-1} \subset S^n$ and the comulitplication is $S^n \rightarrow S^n \vee S^n$ is the pinching operator sending $S^n$ to $S^n/S^{n-1} \simeq S^n \vee S^n$. You can moreover see that for $(X,x)$ a pointed topological space, $\operatorname{Hom}_{hTop_*}(S^n,(X,x)) = [S^n,(X,x)]$ is a group. In fact, that's a way to define $\pi_n(X,x)$.
For coactions maybe you can first see that monoid objects in $\mathbb{Z}-Mod$$\mathbb{Z}$-$\textrm{Mod}$ with the tensor product, are rings. And (left) actions of rings are left modules over rings. If $G$ is a finite group, I think the function ring $\mathcal{C}(G,\mathbb{R})$ would be a (commutative) Hopf algebra, and in particular a cogroup in $\mathbb{R}-Mod$$\mathbb{R}$-$\textrm{Mod}$. And modules that have a coaction on this are exactly representations of $G$.