It’s not hard to check that the subobject classifier $\Omega$ is trivially fibrant, and so its homotopy type is trivial. Orthogonality of $\Omega \to 1$ against a map $i : A \to B$ corresponds to the property that any subobject $A' \to A$ extends to a subobject $B' \to B$ such that $i^*B' = A'$; when $i$ is mono, this is always possible, with canonical solutions given by the direct image $\exists_i A'$ and the dual image $\forall_i A'$.
Nothing here is special to simplicial sets: this argument anpplies equally in any model structure on a topos in which all cofibrations are monomorphisms.
I’m not certain of a precise reference for thisThis argument appears (tersely!) in the literatureproof of Theorem 1. I vaguely recall it appearing in4.3 of Cisinski 2006, Les préfaisceaux comme modèles des types d’homotopie (Presheaves as models for homotopy types), 2006, or (thanks to Tim Campion in one of his related papers, but on a quick skim now I can’t locate itcomments for the precise reference). A similar but slightly harder resultcouple of closely related arguments — firstly the fibrancy of a universe classifying a certain class of fibrations, corresponding to showing that those fibrations extend along trivial cofibrations, and secondly the univalence of this universe — appearsappear in my 2012 paper with Chris Kapulkin, The simplicial model of univalent foundations (after Voevodsky), in Sections 2.1, 2.2, and 3.2.