OK, this is a very broad question so I'll be telegraphic. There is a sequence of increasingly detailed conjectures going by the name GL -- it's really a "program" (harmonic analysis of D$\mathcal{D}$-modules on moduli of bundles) rather than a conjecture -- and only the first of this sequence has been proved (and only for GL_n$GL_n$), but I don't want to get into this.
direct consequences. One application is Gaitsgory's proof of de Jong's conjecture (arXiv:math/0402184). If you prove the ramified geometric Langlands for GL_n$GL_n$, you will recover L. Lafforgue's results (Langlands for function fields), which have lots of consequences (enumerated eg I think in his Fields medal description), which I won't enumerate. (well really you'd need to prove them "well" to get the motivic consequences..) In fact you'll recover much more (like independence of l$l$ results). To me though this is the least convincing motivation..
Original motivation: by understanding the function field version of Langlands you can hope to learn a lot about the Langlands program, working in a much easier setting where you have a chance to go much further. In particular the GLP (the version over C$\mathbb{C}$) has a LOT more structure than the Langlands program -- ie things are MUCH nicer, there are much stronger and cleaner results you can hope to prove, and hope to use this to gain insight into underlying patterns.
- Relations with physics. Once you're over C$\mathbb{C}$, you (by which I mean Beilinson-Drinfeld and Kapustin-Witten) discover lots of deep relations with (at least seemingly) different problems in physics.
- Finally GLP is deeply tied to a host of questions in representation theory, of loop algebras, quantum groups, algebraic groups over finite fields etc. The amazing work of Bezrukavnikov proving a host of fundamental conjectures of Lusztig is based on GLP ideas (and can be thought of as part of the local GLP). (my personal research program with Nadler is to use the same ideas to understand reps of real semisimple Lie groups). This kind of motivation is secretly behind much of the work of BD --- the starting point for all of it is the Beilinson-Bernstein description of reps as D$\mathcal{D}$-modules.