You are asking what is known about the dimension of weight $k$ holomorphic cusp forms for $\mathrm{SL}_2(\mathbb{Z})$, and the multiplicities of Laplace eigenvalues forof weight $0$ and weight $1$ Maass forms for $\mathrm{SL}_2(\mathbb{Z})$. This question is very open ended, likesimilar to asking what is known about the distribution of prime numbers. Well, for holomorphic cusp forms the dimension is known explicitly, and can be found in any introductory textbook (for a more general formula see e.g. Shimura's book Introduction to the arithmetic theory of automorphic functions). For Maass forms, the multiplicities are usually studied by the Selberg trace formula (see e.g. Hejhal's books The Selberg trace formula for $\mathrm{PSL}(2,\mathbb{R})$, Volumes I-II).
I should add that finding which $m_\pi$'s are nonzero is a computationally difficult task. For example, finding the 20th Laplace eigenvalue up to 100 decimal digits is quite challenging (see Booker-Strömbergsson-Venkatesh: Effective computation of Maass cusp forms).